EVIDENCE FOR 2-FOLD HYPERCONJUGATION IN THE SOLVOLYSIS OF 5-(TRIMETHYLSILYL)-2-ADAMANTYL AND 5-(TRIMETHYLSTANNYL)-2-ADAMANTYL SULFONATES

被引：63

作者：

ADCOCK, W ^{[1
]}

COOPE, J ^{[1
]}

SHINER, VJ ^{[1
]}

TROUT, NA ^{[1
]}

机构：

[1] INDIANA UNIV,BLOOMINGTON,IN 47405

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 05期

关键词：

D O I：

10.1021/jo00292a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We wish to report that 5-trimethylsilyl and 5-trimethylstannyl substituents cause unexpectedly large accelerations of the solvolysis of 2-adamantyl p-bromo-benzenesulfonate esters and that these observations confirm the importance of long-range hyperconjugative interactions. © 1990, American Chemical Society. All rights reserved.

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页码：1411 / 1412

页数：2

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