ASYMMETRIC HYDROFORMYLATION OF VINYL-ACETATE BY USE OF CHIRAL BIS(TRIARYLPHOSPHITE) - RHODIUM(I) COMPLEXES

被引：69

作者：

SAKAI, N ^{[1
]}

NOZAKI, K ^{[1
]}

MASHIMA, K ^{[1
]}

TAKAYA, H ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)82286-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(triarylphosphite) ligands 1 - 4 were prepared in optically pure forms from (R)- or (S)-binaphthol and (ArO)2PCl, and their Rh(I) complexes have been used as catalysts for hydroformylation of vinyl acetate. The corresponding branched aldehyde, 2-acetoxypropanal, was given in up to 95% regioselectivity and in 49% ee.

引用

页码：583 / 586

页数：4

共 7 条

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