Ludwig Mond lecture. High-carat gold compounds

被引：637

作者：

Schmidbaur, H

机构：

[1] Anorganisch-chemisches Institut, Tech. Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 1995年 / 24卷 / 06期

关键词：

D O I：

10.1039/cs9952400391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The clustering of mono-coordinate gold(I) cations of the type LAu(+) at Main Group Element nucleation centres leads to a wide variety of aggregates with novel stoichiometries and molecular structures. The unexpected hypercoordination at boron, carbon, nitrogen, oxygen, phosphorus and sulfur frequently observed in these species is rationalized on the basis of significant Au-Au bonding (auriophilicity), which also gives rise to a supramolecular chemistry of simple mono-nuclear two-coordinate gold(I) complexes.

引用

页码：391 / &

页数：11

共 37 条

[1] THE SUPRAMOLECULAR STRUCTURES OF COMPLEX TRI[GOLD(I)]SULFONIUM CATIONS
ANGERMAIER, K
SCHMIDBAUR, H
[J]. CHEMISCHE BERICHTE, 1994, 127 (12) : 2387 - 2391
[2] FURTHER GOLD AGGREGATION AT A PENTANUCLEAR GOLD CLUSTER WITH HYPERCOORDINATE INTERSTITIAL NITROGEN
ANGERMAIER, K
SCHMIDBAUR, H
[J]. INORGANIC CHEMISTRY, 1995, 34 (11) : 3120 - &
[3] CRYSTAL-STRUCTURES OF CHLORO(TRIMETHYLPHOSPHINE)GOLD(I), CHLORO(TRI-(I)PROPYLPHOSPHINE)GOLD(2) AND BIS(TRIMETHYLPHOSPHINE)GOLD(I) CHLORIDE
ANGERMAIER, K
ZELLER, E
SCHMIDBAUR, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 472 (1-2) : 371 - 376
[4] A NEW STRUCTURAL MOTIF OF GOLD CLUSTERING AT OXIDE CENTERS IN THE DICATION [AU6O2(PME3)6]2+
ANGERMAIER, K
SCHMIDBAUR, H
[J]. INORGANIC CHEMISTRY, 1994, 33 (10) : 2069 - 2071
[5] [Anonymous], VLF TRANSMITTERS, V65, P413, DOI [10.1007/s11430.021.9850.7, DOI 10.1007/S11430.021.9850.7]
[6] SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU...AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL]
ASSEFA, Z
MCBURNETT, BG
STAPLES, RJ
FACKLER, JP
ASSMANN, B
ANGERMAIER, K
SCHMIDBAUR, H
[J]. INORGANIC CHEMISTRY, 1995, 34 (01) : 75 - 83
[7] THE GOLD-GERMANIUM BOND IN COORDINATION-COMPOUNDS OF THE TYPE (PH(3)P)(N)AUGECL3 WITH N=1,2 OR 3
BAUER, A
SCHIER, A
SCHMIDBAUR, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (17): : 2919 - 2920
[8] OCTAHEDRAL GOLD CLUSTER - CRYSTAL AND MOLECULAR-STRUCTURE OF HEXAKIS-[TRIS-(P-TOLYL)PHOSPHINE)-OCTAHEDRO-HEXAGOLD BIS(TETRAPHENYLBORATE)
BELLON, P
MANASSER.M
SANSONI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (22): : 2423 - 2427
[9] TETRAKIS[(TRIPHENYLPHOSPHINE)GOLD(I)](TRICYCLOHEXYLPHOSPHINE)BORONIUM TETRAFLUOROBORATE, A NOVEL BORON-CENTERED GOLD CLUSTER
BLUMENTHAL, A
BERUDA, H
SCHMIDBAUR, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (12) : 1005 - 1006
[10] HYPERCOORDINATE CARBON IN TRIGOLDBIS(SILYL)METHANIUM CATIONS
BOMMERS, S
BERUDA, H
DUFOUR, N
PAUL, M
SCHIER, A
SCHMIDBAUR, H
[J]. CHEMISCHE BERICHTE, 1995, 128 (02) : 137 - 142

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