ENERGY-EFFICIENT METHANE-TO-SYNGAS CONVERSION WITH LOW H-2/CO RATIO BY SIMULTANEOUS CATALYTIC REACTIONS OF METHANE WITH CARBON-DIOXIDE AND OXYGEN

被引：107

作者：

CHOUDHARY, VR

RAJPUT, AM

PRABHAKAR, B

机构：

[1] Chemical Engineering Division, National Chemical Laboratory, Pune

来源：

CATALYSIS LETTERS | 1995年 / 32卷 / 3-4期

关键词：

OXIDATION OF METHANE TO SYNGAS; CO2 REFORMING OF METHANE; NIO-CAO CATALYST; COUPLING OF EXOTHERMIC AND ENDOTHERMIC REACTIONS; REACTION OF METHANE WITH O-2 AND CO2;

D O I：

10.1007/BF00813234

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By simultaneous reactions of methane with CO2 and O-2 over NiO-CaO catalyst under certain reaction conditions, it is possible to convert methane into syngas with low H-2/CO ratio (1 < H-2/CO < 2) at above 95% conversion, with 100% CO selectivity and above 90% H-2 selectivity and also with very high CO productivity without catalyst deactivation due to coking for a long period, in a most energy efficient and safe manner, requiring little or no external energy.

引用

页码：391 / 396

页数：6

共 15 条

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