HYDROFORMYLATION OF OLEFINS WITH WATER-SOLUBLE RHODIUM CATALYSTS IN THE PRESENCE OF ALPHA-CYCLODEXTRIN

被引：36

作者：

ANDERSON, JR

CAMPI, EM

JACKSON, WR

机构：

[1] Department of Chemistry, Monash University, Clayton Vic.

来源：

CATALYSIS LETTERS | 1991年 / 9卷 / 1-2期

关键词：

OLEFIN HYDROFORMYLATION; RHODIUM CATALYSIS; WATER SOLUBLE PHOSPHINES; ALPHA-CYCLODEXTRIN;

D O I：

10.1007/BF00769081

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydroformylation of hex-1-ene using a water soluble rhodium catalyst HRh(CO)[PPh2(m-C6H4SO3Na)]3 (HRh(CO)(TPPMS)3) (I), gives lower yields when alpha-cyclodextrin is added to the biphasic reaction system implying an interaction between the cyclodextrin and rhodium catalyst.

引用

页码：55 / 58

页数：4

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