A NOVEL SYNTHESIS OF A GERMENE AND OF A 1,2-DIGERMACYCLOBUTANE VIA A PETERSON-TYPE REACTION

被引：19

作者：

BRAVOZHIVOTOVSKII, D ^{[1
]}

ZHAROV, I ^{[1
]}

KAPON, M ^{[1
]}

APELOIG, Y ^{[1
]}

机构：

[1] TECHNION ISRAEL INST TECHNOL,DEPT CHEM,IL-32000 HAIFA,ISRAEL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 16期

关键词：

D O I：

10.1039/c39950001625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (Me(3)Si)(3)GeLi . 3THF with adamantanone in hexane at -78 degrees C leads via a Peterson-type elimination to bis(trimethylsilyl)adamantylidene germene, which spontaneously dimerizes in a head-to-head fashion to yield 1,1,2,2-tetrakis(trimethylsilyl)-dispiro[3,3'4,4'-biadamantane-1,2-digermacyclobutane] the X-ray structure of which is reported, or which could be trapped by buta-1,3-diene to give the Diels-Alder product.

引用

页码：1625 / 1626

页数：2

共 23 条

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