ENTHALPIES OF MIXING AT 298.15-K OF A METHYL ALKANOATE (FROM ACETATE TO PENTANOATE) WITH NORMAL-ALKANES (NORMAL-TRIDECANE AND NORMAL-PENTADECANE)

被引：16

作者：

ORTEGA, J

MATOS, JS

PENA, JA

机构：

[1] Cátedra de Termodinámica y Fisicoquímica, Escuela Superior de Ingenieros Industrielles, Universidad de Las Palmas de Gran Canaria

来源：

THERMOCHIMICA ACTA | 1990年 / 168卷

关键词：

D O I：

10.1016/0040-6031(90)80631-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess molar enthalpies hE have been measured for the binary liquid mixtures of four methyl alkanoates (acetate, propanoate, butanoate and pentanoate) with two n-alkanes (n-tridecane and n-pentadecane) at 298.15 K, using an isothermal microcalorimeter. All the mixtures studied were endothermic, the hE values for a given n-alkane decreasing with lengthening of the aliphatic chain of the methyl ester. By contrast, the values of hE increased quasi-regularly as the number of carbon atoms in the n-alkane increased. © 1990.

引用

页码：121 / 126

页数：6

共 8 条

[1] ENTHALPIES OF NORMAL-ALKYL ALKANOATES AND 2-ALKANONES IN HOMOLOGOUS SERIES WITH A NORMAL ALKANE [J].

DUSART, O ;

PIEKARSKI, S ;

GROLIER, JPE .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1979, 76 (05) :433-437

[2]

GREEN JR, 1978, STATISTICAL TREATMEN

[3] THERMODYNAMICS OF ESTER-CONTAINING MIXTURES - EXCESS ENTHALPIES AND EXCESS VOLUMES FOR ALKYL ACETATES AND ALKYL BENZOATES + ALKANES, + BENZENE, + TOLUENE, AND + ETHYLBENZENE [J].

GROLIER, JPE ;

BALLET, D ;

VIALLARD, A .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1974, 6 (09) :895-908

[4]

McGlashan M.L., 1969, J CHEM THERMODYN, V1, P589, DOI [10.1016/0021-9614(69)90019-6, DOI 10.1016/0021-9614(69)90019-6]

[5] EXCESS MOLAR ENTHALPIES OF METHYL ALKANOATES + NORMAL-NONANE AT 298.15-K [J].

ORTEGA, J ;

MATOS, JS ;

PENA, JA .

THERMOCHIMICA ACTA, 1990, 160 (02) :337-342

[6] ANALYSIS OF EXCESS-ENTHALPIES OF ESTER+ 1-CHLOROALKANES WITH 2 GROUP CONTRIBUTION MODELS - PRIMARY PARAMETERS [J].

ORTEGA, J ;

MATOS, JS ;

PAZANDRADE, MI ;

FERNANDEZ, J ;

PIAS, L .

FLUID PHASE EQUILIBRIA, 1988, 43 (2-3) :295-316

[7]

Riddick JA., 1986, PHYS PROPERTIES METH

[8]

TIMMERMANS J, 1965, PHYSICOCHEM CONSTANT, V2

← 1 →