EVALUATION OF THE INTERFACIAL-TENSION BETWEEN HIGH-MOLECULAR-WEIGHT POLYCARBONATE AND PMMA RESINS WITH THE IMBEDDED FIBER RETRACTION TECHNIQUE

被引:62
作者
CARRIERE, CJ
COHEN, A
机构
[1] Materials Science and Development Laboratory, Central Research, The Dow Chemical Company, Midland
关键词
D O I
10.1122/1.550212
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
The interfacial tension between molten, high molecular weight samples of polycarbonate and poly(methyl methacrylate) was measured using the imbedded fiber retraction (IFR) technique. A value of 1.44 +/- 0.16 dyn/cm was measured at 240-degrees-C. This value was obtained on commercial resins with zero-shear bulk viscosities and at a temperature typically encountered in the processing of blends and/or composites. Refinements to the IFR method were implemented which reduced the experimentation time. Consequently, measurements of the interfacial tension can now be routinely obtained in several hours for materials with zero-shear bulk viscosities on the order of 10(4) Pa s.
引用
收藏
页码:205 / 212
页数:8
相关论文
共 17 条
[11]   INTERFACIAL TENSION BETWEEN POLYMER LIQUIDS [J].
ROE, RJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1969, 31 (02) :228-&
[12]  
SAKAI T, 1965, POLYMER, V6, P659
[13]  
Tomotika S., 1935, P ROYAL SOC LONDON A, V150, P322, DOI DOI 10.1098/RSPA.1935.0104
[14]  
Wu, 1971, J POLYM SCI C, V34, P19, DOI DOI 10.1002/POLC.5070340105
[15]   SURFACE AND INTERFACIAL TENSIONS OF POLYMER MELTS .I. POLYETHYLENE, POLYISOBUTYLENE, AND POLYVINYL ACETATE [J].
WU, S .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1969, 31 (02) :153-&
[16]  
Wu S., 1982, POLYM INTERFACE ADHE, P109
[17]  
Wu S. Y., 1989, Potentialities of agricultural engineering in rural development. Proceedings of the international symposium on agricultural engineering (89-ISAE), Beijing, China, 12-15 September 1989., P411