IN-SITU NMR AND EXAFS STUDIES OF THE HOMOGENEOUS ALKENE OLIGOMERIZATION CATALYST NI(COD)2-PH2PCH2C(CF3)2OH

被引：10

作者：

ANDREWS, P ^{[1
]}

EVANS, J ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 16期

关键词：

D O I：

10.1039/c39930001246

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NMR and extended X-ray absorption fine structure (EXAFS) studies indicate that the nickel coordination sphere of the highly active alkene oligomerisation catalyst formed on addition of Ph2PCH2C(CF3)2OH to Ni(cod)2 (cod = cycloocta-1,5-diene) is Ni{Ph2PCH2C(CF3)2O}H{Ph2PCH2C(CH3)2OH}.

引用

页码：1246 / 1248

页数：3

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