A new highly efficient method for the synthesis of Ti-Beta zeolite oxidation catalyst

被引：41

作者：

Camblor, MA ^{[1
]}

Constantini, M ^{[1
]}

Corma, A ^{[1
]}

Esteve, P ^{[1
]}

Gilbert, L ^{[1
]}

Martinez, A ^{[1
]}

Valencia, S ^{[1
]}

机构：

[1] CRIT,RHONE POULENC INDUSTRIALISAT,F-69192 ST FONS,FRANCE

来源：

APPLIED CATALYSIS A-GENERAL | 1995年 / 133卷 / 02期

关键词：

titanium beta synthesis; titania-silica cogels; oxidation catalysts; alkene oxidation; phenol hydroxylation;

D O I：

10.1016/0926-860X(95)00252-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new method for the efficient synthesis of zeolite Ti-Beta oxidation catalysts is reported. High yields of zeolite are obtained by carrying out the synthesis in a dense system, by crystallizing a mixture obtained by wetness impregnation of TiO2-SiO2 cogels. This method requires lower amounts of organic structure directing agent, and materials with low aluminium content can be synthesized. The crystallization mechanism involves transport in the liquid phase, indicating that a direct transformation of the cogel does not occur. Spectroscopic characterization techniques and catalytic tests demonstrate that Ti is incorporated into framework sites.

引用

页码：L185 / L189

页数：5

共 11 条

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