VIBRATIONAL-MODES AND THE DYNAMIC SOLVENT EFFECT IN ELECTRON AND PROTON-TRANSFER

被引：280

作者：

BARBARA, PF ^{[1
]}

WALKER, GC ^{[1
]}

SMITH, TP ^{[1
]}

机构：

[1] THREE M CO,GRAPH RES LAB,ST PAUL,MN 55133

来源：

SCIENCE | 1992年 / 256卷 / 5059期

关键词：

D O I：

10.1126/science.256.5059.975

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

This article primarily reviews recent work on ultrafast experiments on excited state intramolecular electron and proton transfer, with an emphasis on experiments on chemical systems that have been analyzed theoretically. In particular, those systems that have been quantitatively characterized by static spectroscopy, which provides detailed information about the reaction potential energy surface and about other parameters that are necessary to make a direct comparison to theoretical predictions, are described.

引用

页码：975 / 981

页数：7

共 62 条

[1] TRANSIENT KINETICS OF CHEMICAL-REACTIONS WITH BOUNDED DIFFUSION PERPENDICULAR TO THE REACTION COORDINATE - INTRAMOLECULAR PROCESSES WITH SLOW CONFORMATIONAL-CHANGES [J].