CHARACTERIZATION OF AMORPHOUS SUBSTANCES BY STUDYING ISOTOPICALLY LABELED COMPOUNDS WITH FAB-MS - EVIDENCE FOR EXTRUSION OF TRIANGULAR MO3IV CLUSTERS FROM A MIXTURE OF (MOS3)-MO-92 AND (MOS3)-MO-100 BY REACTION WITH OH-

被引：31

作者：

MULLER, A

FEDIN, V

HEGETSCHWEILER, K

AMREIN, W

机构：

[1] SWISS FED INST TECHNOL,ANORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

[2] SWISS FED INST TECHNOL,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001795

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As the extrusion of Mo-92(3) and Mo-100(3) cluster species is the absolutely dominating pathway for the reaction of a mixture of amorphous (MoS3)-Mo-92 and (MoS3)-Mo-100 with an aqueous solution of KOH, it can be concluded that the material is built up by Mo(n) (n greater-than-or-equal-to 3) cluster units.

引用

收藏

页码：1795 / 1798

页数：4

相关论文

共 17 条

[1]

Chianelli R., 1982, INT REV PHYS CHEM, V2, P127

[2] EXAFS STUDIES OF AMORPHOUS MOLYBDENUM AND TUNGSTEN TRISULFIDES AND TRISELENIDES [J].

CRAMER, SP ;

LIANG, KS ;

JACOBSON, AJ ;

CHANG, CH ;

CHIANELLI, RR .

INORGANIC CHEMISTRY, 1984, 23 (09) :1215-1221

[3] RADIAL-DISTRIBUTION FUNCTIONS .5. STRUCTURAL STUDIES ON NON-CRYSTALLINE MOLYBDENUM TRISULFIDE, TUNGSTEN TRISULFIDE, AND MOLYBDENUM TRISELENIDE [J].

DIEMANN, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 432 (05) :127-135

[4] TRIANGULAR THIOCOMPLEXES OF MOLYBDENUM - REACTIONS WITH HALOGENS, HYDROHALOGEN ACIDS AND PHOSPHINES [J].

FEDIN, VP ;

SOKOLOV, MN ;

MIRONOV, YV ;

KOLESOV, BA ;

TKACHEV, SV ;

FEDOROV, VY .

INORGANICA CHIMICA ACTA, 1990, 167 (01) :39-45

[5] DIETHYLDITHIOCARBAMATE TRIANGULAR THIO-COMPLEXES OF MOLYBDENUM - SYNTHESIS AND AN X-RAY STRUCTURAL STUDY OF [MO3S7(S2CNET2)3]CL [J].

FEDIN, VP ;

SOKOLOV, MN ;

GERASKO, OA ;

VIROVETS, AV ;

PODBEREZSKAYA, NV ;

FEDOROV, VY .

INORGANICA CHIMICA ACTA, 1992, 192 (02) :153-156

[6]

Fedorov V.E., 1985, RUSS CHEM REV+, V54, P408, DOI [DOI 10.1070/RC1985V054N04ABEH003064, 10.1070/rc1985v054n04abeh003064]

[7] A NEW SYNTHETIC PATHWAY FOR TRIS-MU-DISULFIDO-MU-3-THIO-TRIANGULO-TRIMOLYBDENUM(IV) COMPLEXES - PREPARATION, CHARACTERIZATION AND STRUCTURE OF [MO3S(S2)3(OOC-CHS-CH2-COOH)3]2- [J].

HEGETSCHWEILER, K ;

KELLER, T ;

ZIMMERMANN, H ;

SCHNEIDER, W ;

SCHMALLE, H ;

DUBLER, E .

INORGANICA CHIMICA ACTA, 1990, 169 (02) :235-243

[8] IDENTIFICATION AND CHARACTERIZATION OF TRINUCLEAR MOLYBDENUM-SULFUR CLUSTERS BY FAST-ATOM-BOMBARDMENT (FAB) MASS-SPECTROMETRY [J].

HEGETSCHWEILER, K ;

KELLER, T ;

AMREIN, W ;

SCHNEIDER, W .

INORGANIC CHEMISTRY, 1991, 30 (04) :873-876

[9] AMORPHOUS MOLYBDENUM TRISULFIDE - NEW LITHIUM BATTERY CATHODE [J].

JACOBSON, AJ ;

CHIANELLI, RR ;

RICH, SM ;

WHITTINGHAM, MS .

MATERIALS RESEARCH BULLETIN, 1979, 14 (11) :1437-1448

[10] NONMOLECULAR METAL CHALCOGENIDE HALIDE SOLIDS AND THEIR MOLECULAR CLUSTER ANALOGS [J].

LEE, SC ;

HOLM, RH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (08) :840-856