SYNTHESIS OF FURAN-2,5-DICARBALDEHYDE BY OXIDATION OF 5-SILYLOXYMETHYL-2-FURFURAL

被引：11

作者：

COTTIER, L

DESCOTES, G

LEWKOWSKI, J

机构：

[1] UNIV LYON 1,CHIM ORGAN LAB 2,CNRS,URA 463,F-69622 VILLEURBANNE,FRANCE

[2] UNIV LODZ,INST CHEM,DEPT CHEM,PL-90135 LODZ,POLAND

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 07期

关键词：

D O I：

10.1080/00397919408020768

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of alkyl silyl ethers of 5-hydroxymethyl-2-furfural to furane-2,5-dicarbaldehyde is promoted by N-bromosuccinimide in the presence of azoisobutyronitrile. The influence of solvent has been studied. Using 1,2-dichloromethane or dodecane as solvent, good yields are obtained from the trimethylsilyl or tert-butyldimethylsilyl derivatives.

引用

页码：939 / 944

页数：6

共 18 条

[1] PROTECTION OF HYDROXYL GROUPS AS TERT-BUTYLDIMETHYLSILYL DERIVATIVES [J].