THALLIUM(I)-BIS(TRIMETHYLSILYL)AMIDE

被引：34

作者：

KLINKHAMMER, KW ^{[1
]}

HENKEL, S ^{[1
]}

机构：

[1] UNIV STUTTGART,INST ORGAN CHEM,D-70550 STUTTGART,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 480卷 / 1-2期

关键词：

SILICON; THALLIUM; AMIDE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87113-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of LiN(SiMe3)2 with TlCl in toluene yields the bis(trimethylsilyl)amino derivative of thallium(I) (1). In the gaseous phase and in benzene solution the compound is mainly monomeric, whereas in the solid state the amide 1 consists of cyclic dimers, which are linked to infinite chains by intermolecular Tl ... Tl contacts.

引用

页码：167 / 171

页数：5

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