FUNCTIONALIZED 1,1-ETHENEDITHIOLATES AS LIGANDS .3. PALLADIUM(II) AND PLATINUM(II) COMPLEXES WITH FERROCENYL-SUBSTITUTED 1,1-ETHENEDITHIOLATE LIGANDS - CRYSTAL-STRUCTURE ANALYSES OF CIS-(PH(3)P)(2)M[S2C=CH-C(O)-(ETA(5)-C5H4)FE(ETA(5)-C5H5)] (M=PD,PT)

被引：23

作者：

BUCHWEITZ, J

GOMPPER, R

POLBORN, K

ROBL, C

SAILER, MT

WEIGAND, W

机构：

[1] UNIV MUNICH,INST ORGAN CHEM,D-80333 MUNICH,GERMANY

[2] UNIV MUNICH,INST ANORGAN CHEM,D-80333 MUNICH,GERMANY

来源：

CHEMISCHE BERICHTE | 1994年 / 127卷 / 01期

关键词：

FERROCENE DERIVATIVES; 1,1-ETHENEDITHIOLATE COMPLEXES; GROUP 10 METAL COMPLEXES; HETERODIMETALLIC COMPOUNDS; HETEROTRIMETALLIC COMPOUNDS;

D O I：

10.1002/cber.19941270105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ferrocenyl-substituted mono- (3) and 1,1'-bis-dithiocarboxylic acids (4) have been prepared. These acids react with L(2)MCl(2) (M=Pd,Pt; L=PEt(3), PPh(3), and 1/2 dppe) in the presence of sodium acetate to give the cis heterodi- and heterotrimetallic complexes cis-L(2)M[S2C=CH-C(O)-(eta(5)-C5H4)Fe(eta(5)-C5H5)] (5a: M = Pd, L = PPh(3); 5b: M = Pt, L = PPh3; 5c: M=Pt, L=1/2 dppe) and [cis-L(2)MS(2)C= CH-C(O)-(eta(5)-C5H4)]Fe-2 (6a: M = Pd, L = PPh(3); 6b: M = Pt, L = PEt(3); 6c: M = Pt, L = PPh(3); 6d: M = Pt, L = 1/2 dppe). The structures of 5a and 5b have been determined by single-crystal X-ray diffraction.

引用

页码：23 / 26

页数：4

共 23 条

[1] EFFECT OF CHELATE-RING SIZE ON SPECTROSCOPIC AND CHEMICAL PROPERTIES OF METHYLPLATINUM(II) COMPLEXES OF DITERTIARY PHOSPHINES PH-2P-[CH-2]-NPPH-2(N=1,2, OR 3) [J].