GROUP-6 ANIONIC MU-HYDRIDE COMPLEXES [HCR2(CO)10]-, [HMO2(CO)10]-, [HW2(CO)10]- - NEW CATALYSTS FOR HYDROGENATION AND HYDROSILYLATION

被引：37

作者：

FUCHIKAMI, T

UBUKATA, Y

TANAKA, Y

机构：

[1] Sagami Chemical Research Center, Sagamihara, Kanagawa, 229

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92043-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Group 6 anionic mu-hydride complexes catalyze hydrogenation of conjugated olefins, aldehydes, ketoesters, and alkynes, and hydrosilylation of aldehydes and conjugated olefins with high regio- and stereoselectivity. Ketones are converted into silyl ethers and silyl enol ethers with monohydrosilanes and dihydrosilanes, respectively.

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页码：1199 / 1202

页数：4

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