THERMODYNAMICS OF BINARY-MIXTURES CONTAINING ORGANIC CARBONATES .4. LIQUID LIQUID EQUILIBRIA OF DIMETHYL CARBONATE + SELECTED N-ALKANES

被引：63

作者：

GONZALEZ, JA ^{[1
]}

GARCIA, I ^{[1
]}

COBOS, JC ^{[1
]}

CASANOVA, C ^{[1
]}

机构：

[1] UNIV VALLADOLID,DEPT FIS APLICADA,E-47071 VALLADOLID,SPAIN

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1991年 / 36卷 / 02期

关键词：

D O I：

10.1021/je00002a009

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Liquid-liquid equilibrium (LLE) data are reported for dimethyl carbonate + n-decane, + n-dodecane, + n-tetradecane, or + n-hexadecane at atmospheric pressure, between 277 K and the upper critical temperatures. The solubility curve of pure solid n-hexadecane in liquid dimethyl carbonate is also presented. The coexistence curves are very asymmetrical with respect to mole fraction, the asymmetry increasing with the size of the n-alkane. The critical solution points vary almost linearly with the number of carbon atoms of the n-alkane. The data are used in the framework of regular solution theory to obtain the solubility parameter of dimethyl carbonate.

引用

页码：162 / 164

页数：3

共 18 条

[1]

[Anonymous], 1985, IUPAC CHEM DATA SER

[2] CRITICAL SOLUTION TEMPERATURES OF LIQUID-MIXTURES AND THE HYDROPHOBIC EFFECT [J].

BALASUBRAMANIAN, D ;

MITRA, P .

JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (21) :2724-2727

[3] THERMODYNAMICS OF BINARY-MIXTURES CONTAINING ORGANIC CARBONATES .2. ISOTHERMAL VAPOR-LIQUID-EQUILIBRIA FOR DIMETHYL CARBONATE + CYCLOHEXANE, + BENZENE, OR + TETRACHLOROMETHANE [J].

COCERO, MJ ;

MATO, F ;

GARCIA, I ;

COBOS, JC ;

KEHIAIAN, HV .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (01) :73-76

[4] THERMODYNAMICS OF BINARY-MIXTURES CONTAINING ORGANIC CARBONATES .3. ISOTHERMAL VAPOR LIQUID EQUILIBRIA FOR DIETHYL CARBONATE + CYCLOHEXANE, + BENZENE, OR + TETRACHLOROMETHANE [J].

COCERO, MJ ;

MATO, F ;

GARCIA, I ;

COBOS, JC .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (04) :443-445

[5] ACETONE IMPURITY EFFECTS ON THE BINARY FLUID MIXTURE METHANOL-CYCLOHEXANE [J].

COHN, RH ;

JACOBS, DT .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (02) :856-859

[6] THERMODYNAMICS OF BINARY-MIXTURES CONTAINING ORGANIC CARBONATES .1. EXCESS-ENTHALPIES OF DIMETHYL CARBONATE + HYDROCARBONS OR + TETRACHLOROMETHANE [J].

GARCIA, I ;

COBOS, JC ;

GONZALEZ, JA ;

CASANOVA, C ;

COCERO, MJ .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (04) :423-426

[7]

GARCIA I, 1987, INT DATA SER SEL D A, P164

[8] SHAPE OF THE COEXISTENCE CURVE IN THE PERFLUOROMETHYLCYCLOHEXANE-CARBON TETRACHLORIDE SYSTEM [J].

GOPAL, R ;

RICE, OK .

JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (12) :2428-2431

[9]

HILDEBRAND JH, 1962, INT SERIES CHEM

[10] THERMODYNAMICS OF BINARY-LIQUID ORGANIC MIXTURES [J].

KEHIAIAN, HV .

PURE AND APPLIED CHEMISTRY, 1985, 57 (01) :15-30

← 1 2 →