CHARACTERIZATION OF THE CATIONIC EXCHANGES IN A-ZEOLITES BY MEANS OF THE VIBRATIONAL FREQUENCIES OF THE CATIONS

被引：16

作者：

BOUMIZ, A ^{[1
]}

CARTIGNY, J ^{[1
]}

DELARA, EC ^{[1
]}

机构：

[1] UNIV PARIS 06,CNRS,RECH PHYS LAB,4 PL JUSSIEU,TOUR 22,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 13期

关键词：

D O I：

10.1021/j100192a044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The far-infrared spectra of A-type zeolite samples show broad bands sensitive to cationic exchange. We present the far-infrared spectra of five A zeolites with Li+, Na+, K+, or Ca2+ cations. The vibrational frequencies of the exchangeable cations with respect to the anionic framework have been calculated, taking in account the ions of eight sodalite units. In the potential interaction between cation and framework (electrostatic, polarization, dispersion, and repulsion), the repulsion constants are determined by a combination method, and the effective ionic charges by the orbital electronegativity method.

引用

页码：5419 / 5424

页数：6

共 31 条

[1] THE STRUCTURE OF DEHYDRATED ZEOLITE 3A (SI/AL = 1.01) BY NEUTRON PROFILE REFINEMENT
ADAMS, JM
HASELDEN, DA
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1983, 47 (02) : 123 - 131
[2] FREQUENCY AND INTENSITY CONSIDERATIONS IN THE FAR-INFRARED SPECTROSCOPY OF FAUJASITE ZEOLITES - EXPERIMENT AND THEORY - METAL CATION VIBRATIONAL ASSIGNMENTS, SITE LOCATIONS, AND POPULATIONS
BAKER, MD
GODBER, J
OZIN, GA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (11) : 3033 - 3043
[3] ION EXCHANGE AND THE THERMODYNAMICS OF INTRACRYSTALLINE SORPTION .1. ENERGETICS OF OCCLUSION OF ARGON AND NITROGEN BY FAUJASITE-TYPE CRYSTALS
BARRER, RM
STUART, WI
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1959, 249 (1259): : 464 - 483
[4] BERAN S, 1979, J AM CHEM SOC, V101, P2538
[5] ELECTRONEGATIVITIES AND HARDNESSES OF THE MAIN GROUP ELEMENTS FROM DENSITY FUNCTIONAL THEORY - DEPENDENCE ON THE HYBRIDIZATION OF THE CHEMICAL-BOND
BOHM, MC
SCHMIDT, PC
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (10): : 913 - 919
[6] Breck D. W, 1974, ZEOLITE MOL SIEVES
[7] DEFECT ENERGETICS IN ALPHA-AL2O3 AND RUTILE TIO2
CATLOW, CRA
JAMES, R
MACKRODT, WC
STEWART, RF
[J]. PHYSICAL REVIEW B, 1982, 25 (02): : 1006 - 1026
[8] SIMULATING SILICATE STRUCTURES AND THE STRUCTURAL CHEMISTRY OF PYROXENOIDS
CATLOW, CRA
THOMAS, JM
PARKER, SC
JEFFERSON, DA
[J]. NATURE, 1982, 295 (5851) : 658 - 662
[9] FIRROR RL, 1978, J AM CHEM SOC, V100, P3091
[10] Flanigen E.M., 1974, ADV CHEM SER, P201, DOI DOI 10.1021/BA-1971-0101.CH016

← 1 2 3 4 →