A FACILE ENTRY TO MACROCYCLIC DISULFIDES - AN EFFICIENT SYNTHESIS OF REDOX-SWITCHED CROWN-ETHERS

被引：71

作者：

RAMESHA, AR ^{[1
]}

CHANDRASEKARAN, S ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 06期

关键词：

D O I：

10.1021/jo00085a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An interesting sulfur transfer reaction with benzyltriethylammonium tetrathiomolybdate has been used efficiently for the synthesis of macrocyclic disulfides. This methodology has been extended to a high-yield synthesis of ''redox-switched'' crown ethers which have potential application for selective ion transport across liquid membranes.

引用

页码：1354 / 1357

页数：4

共 33 条

[1] REDOX RESPONSIVE MACROCYCLIC RECEPTOR MOLECULES CONTAINING TRANSITION-METAL REDOX CENTERS [J].

BEER, PD .

CHEMICAL SOCIETY REVIEWS, 1989, 18 (04) :409-450

[2] MACROCYCLIC POLYETHER SULFIDE SYNTHESES - PREPARATION OF THIA(CROWN-6, CROWN-7 AND CROWN-8) COMPOUNDS [J].

BRADSHAW, JS ;

REEDER, RA ;

THOMPSON, MD ;

FLANDERS, ED ;

CARRUTH, RL ;

IZATT, RM ;

CHRISTENSEN, JJ .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (01) :134-136

[3] MACROCYCLIC POLYETHER SULFIDE SYNTHESES - PREPARATION OF THIA-CROWN-3,4, AND 5 COMPOUNDS (1) [J].

BRADSHAW, JS ;

HUI, JY ;

HAYMORE, BL ;

CHRISTEN.JJ ;

IZATT, RM .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1973, 10 (01) :1-4

[4] PREPARATION OF OXATHIAPENTADECANES [J].

BRADSHAW, JS ;

HAYMORE, BL ;

IZATT, RM ;

CHRISTENSEN, JJ .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (10) :1510-1511

[5]

BRADSHAW JS, 1974, J HETEROCYCLIC CHEM, V45, P11

[6]

BYERS W, 1973, BIOCHIM BIOPHYS ACTA, V38, P310

[7] PH-DEPENDENT METAL-ION SELECTIVITY BY A CROWN-ETHER CARBOXYLIC-ACID [J].

CHANG, CA ;

TWU, J ;

BARTSCH, RA .

INORGANIC CHEMISTRY, 1986, 25 (03) :396-398

[8] COMPETITIVE TRANSPORT OF ALKALI-METAL IONS FROM AQUEOUS-MEDIA INTO TOLUENE SOLUTIONS OF 2-(SYM-DIBENZO-16-CROWN-5-OXY)-DECANOIC ACID - A COMPARATIVE-STUDY [J].

CHAREWICZ, WA ;

BARTSCH, RA .

JOURNAL OF MEMBRANE SCIENCE, 1983, 12 (03) :323-333

[9] SULFUR-CONTAINING LARGE-RING COMPOUNDS - PREPARATION OF 4,7,13,16-TETRAOXA-1,10-DITHIACYCLOOCTADECANE AND RELATED COMPOUNDS [J].

DANN, JR ;

GATES, JW ;

CHIESA, PP .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (06) :1991-&

[10]

DARIS FO, 1948, J AM CHEM SOC, V69, P2611

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