TRANSITION-METAL COMPLEXES OF 1,10-PHENANTHROLINE-5,6-DIONE AS EFFICIENT MEDIATORS FOR THE REGENERATION OF NAD+ IN ENZYMATIC-SYNTHESIS

被引：45

作者：

HILT, G ^{[1
]}

STECKHAN, E ^{[1
]}

机构：

[1] UNIV BONN,INST BIOCHEM & ORGAN CHEM,D-53121 BONN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期

关键词：

D O I：

10.1039/c39930001706

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexation of 1,10-phenanthroline-5,6-dione by transition metals increases the catalytic turnover frequency by a factor of up to 17 for the aerobic-chemical and a factor of 14 for the indirect electrochemical NAD+-regeneration for HLADH catalysed alcohol oxidations in comparison with the uncomplexed phenanthrolinediones.

引用

页码：1706 / 1707

页数：2

共 19 条

[1] ELECTROCHEMICAL REGENERATION OF NAD+ - A NEW EVALUATION OF ITS ACTUAL YIELD [J].

BONNEFOY, J ;

MOIROUX, J ;

LAVAL, JM ;

BOURDILLON, C .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 :941-950

[2]

DAVIES HG, 1989, TECHNIQUES CHEM, V10, pCH4

[3] AN ELECTRODE MODIFIED WITH POLYMER-BOUND DOPAMINE WHICH CATALYZES NADH OXIDATION [J].

DEGRAND, C ;

MILLER, LL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5728-5732

[4]

FASSOUNE A, 1990, BIOTECHNOL BIOENG, V33, P935

[5]

FREDE M, 1993, THESIS BONN

[6]

FREDE M, IN PRESS HDB ENZYME, pCH6

[7] CHEMICALLY MODIFIED ELECTRODES FOR THE ELECTROCATALYTIC OXIDATION OF NICOTINAMIDE COENZYMES [J].

GORTON, L .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :1245-1258

[8]

Huck H., 1981, ANGEW CHEM, V93, P421

[9] EFFICIENT NAD(+)-REGENERATION SYSTEM WITH HETEROCYCLIC ORTHO-QUINONES AND MOLECULAR-OXYGEN CATALYZED BY DIAPHORASE [J].

ITOH, S ;

MITA, N ;

OHSHIRO, Y .

CHEMISTRY LETTERS, 1990, (10) :1949-1952

[10] HETEROCYCLIC ORTHO-QUINONES - MEDIATOR FOR ELECTROCHEMICAL OXIDATION OF NADH [J].

ITOH, S ;

FUKUSHIMA, H ;

KOMATSU, M ;

OHSHIRO, Y .

CHEMISTRY LETTERS, 1992, (08) :1583-1586

← 1 2 →