TRANSPORT OF COPPER THROUGH A SUPPORTED LIQUID MEMBRANE

被引:23
作者
TAKAHASHI, K [1 ]
TAKEUCHI, H [1 ]
机构
[1] NAGOYA UNIV,DEPT CHEM ENGN,NAGOYA,AICHI 464,JAPAN
关键词
COPPER AND ALLOYS - Transport Properties - COPPER COMPOUNDS - SEPARATION;
D O I
10.1252/jcej.18.205
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
An experimental study was carried out to elucidate the mechanism of ion transport through supported liquid membranes (SLM) and to approach liquid membrane separation in industrial uses. Two channels of 1 mm depth were prepared on both sides of a porous polymer sheet supporting extractant solution. Copper was permeated from the feed solution of copper sulfate into a strip solution of sulfuric acid through an SLM impregnated with kerosene solution of LIX65N as membrane solution. To stabilize the SLM the membrane solution was forced to flow with the strip solution. Such an operation mode allows enhancement of the rate of copper permeation, which is interpreted by a reduction in resistance for strip reaction due to sweeping the strip surface of the SLM with the membrane solution stream.
引用
收藏
页码:205 / 211
页数:7
相关论文
共 16 条
[1]  
BABCOCK WC, 1983, ISEC 83, P373
[2]  
HARDWICK TJ, 1983, ISEC 83, P397
[3]   SELECTIVE COPPER RECOVERY WITH 2 TYPES OF LIQUID MEMBRANES [J].
LEE, KH ;
EVANS, DF ;
CUSSLER, EL .
AICHE JOURNAL, 1978, 24 (05) :860-868
[4]  
NOBLE RD, 1983, ISEC 83, P374
[5]  
SHERWOOD TK, 1975, MASS TRANSFER, P25
[6]  
TAGA J, 1981, 46TH ANN M SOC CHEM, P712
[7]   EFFECT OF EMULSIFYING AGENT ON EXTRACTION RATE OF COPPER BY LIX65N [J].
TAKAHASHI, K ;
OHTSUBO, F ;
TAKEUCHI, H .
KAGAKU KOGAKU RONBUNSHU, 1982, 8 (04) :399-403
[8]  
TAKAHASHI K, 1984, KAGAKU KOGAKU RONBUN, V10, P543
[9]  
TAKAHASHI K, 1985, KAGAKU KOGAKU RONBUN, V11, P110
[10]   RATES OF COPPER-EXTRACTION BY LIX65N [J].
TAKAHASHI, K ;
TAKEUCHI, H .
KAGAKU KOGAKU RONBUNSHU, 1984, 10 (04) :409-414