THE STRUCTURE OF THE SURFACE METHOXY SPECIES ON NI(111)

被引：31

作者：

SCHAFF, O

HESS, G

FRITZSCHE, V

FERNANDEZ, V

SCHINDLER, KM

THEOBALD, A

HOFMANN, P

BRADSHAW, AM

DAVIS, R

WOODRUFF, DP

机构：

[1] MAX PLANCK GESELL, FRITZ HABER INST, D-14195 BERLIN, GERMANY

[2] UNIV WARWICK, DEPT PHYS, COVENTRY CV4 7AL, W MIDLANDS, ENGLAND

来源：

SURFACE SCIENCE | 1995年 / 331卷

关键词：

ALKOXIDES; CHEMISORPTION; COPPER; PHOTOELECTRON DIFFRACTION; SINGLE CRYSTAL SURFACES; SOLID-GAS INTERFACES; SURFACE STRUCTURE;

D O I：

10.1016/0039-6028(95)00202-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using photoelectron diffraction in the scanned energy mode the structure of the surface methoxy species (CH3O-) on Ni{111} has been determined. Bonding occurs at the "fcc" threefold symmetric hollow site with a Ni-O bond length of 1.94 Angstrom; the O-C axis is perpendicular to the surface.

引用

页码：201 / 206

页数：6

共 27 条

[1]

BRADSHAW AM, IN PRESS APPLICATION

[2] THE ADSORPTION AND REACTION OF METHANOL ON OXIDIZED COPPER(111) STUDIED BY FOURIER-TRANSFORM REFLECTION ABSORPTION INFRARED-SPECTROSCOPY [J].

CHESTERS, MA ;

MCCASH, EM .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1987, 43 (12) :1625-1630

[3] DETERMINATION OF THE ORIENTATION OF METHOXY ON CU(111) USING X-RAY PHOTOELECTRON DIFFRACTION [J].

DECARVALHO, AV ;

ASENSIO, MC ;

WOODRUFF, DP .

SURFACE SCIENCE, 1992, 273 (03) :381-384

[4] OBSERVATION OF A METHOXY SPECIES ON NI(111) BY HIGH-RESOLUTION ELECTRON ENERGY-LOSS SPECTROSCOPY [J].

DEMUTH, JE ;

IBACH, H .

CHEMICAL PHYSICS LETTERS, 1979, 60 (03) :395-399

[5] A HIGH-FLUX TOROIDAL GRATING MONOCHROMATOR FOR THE SOFT-X-RAY REGION [J].

DIETZ, E ;

BRAUN, W ;

BRADSHAW, AM ;

JOHNSON, RL .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1985, 239 (02) :359-366

[6] THE ELECTRONIC-STRUCTURE AND ORIENTATION OF THE SURFACE METHOXY SPECIES ON NI(111) [J].

ERSKINE, JL ;

BRADSHAW, AM .

CHEMICAL PHYSICS LETTERS, 1980, 72 (02) :260-263

[7] CALCULATION OF AUGER-ELECTRON DIFFRACTION AT A NI(111) SURFACE [J].

FRITZSCHE, V .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1990, 2 (49) :9735-9747

[8] DIRECT PHOTOELECTRON-DIFFRACTION METHOD FOR ADSORBATE STRUCTURAL DETERMINATIONS [J].

FRITZSCHE, V ;

WOODRUFF, DP .

PHYSICAL REVIEW B, 1992, 46 (24) :16128-16134

[9] LINEAR-SUPERPOSITION METHOD FOR THE MULTIPLE-SCATTERING PROBLEM IN LOW-ENERGY-PHOTOELECTRON DIFFRACTION [J].

FRITZSCHE, V ;

PENDRY, JB .

PHYSICAL REVIEW B, 1993, 48 (12) :9054-9057

[10] CONSEQUENCES OF A FINITE-ENERGY RESOLUTION FOR PHOTOELECTRON DIFFRACTION SPECTRA [J].

FRITZSCHE, V .

SURFACE SCIENCE, 1992, 265 (1-3) :187-195

← 1 2 3 →