Crystal structure of 4-cyano-4'-n-undecylbiphenyl

被引:15
作者
Manisekaran, T
Bamezai, RK
Sharma, NK
Prasad, JS
机构
[1] UNIV MYSORE,DEPT STUDIES PHYS,MYSORE 570006,KARNATAKA,INDIA
[2] INDIAN INST TECHNOL,REG SOPHISTICATED INSTRUMENTAT CTR,MADRAS 600036,TAMIL NADU,INDIA
[3] UNIV JAMMU,DEPT CHEM,JAMMU 570006,INDIA
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1995年 / 268卷
关键词
crystal structure; 4-cyano-4'-n-undecylbiphenyl; smectic A;
D O I
10.1080/10587259508030991
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The structure 4-cyano-4'-decylbiphenyl is reported in our paper on page 83 of this volume.(1) To achieve greater insight into molecular packing in homologous series of 4-cyano-4-n-alkylbiphenyl(2-3) the structure of the higher homolog 4-cyano-4'-n-undecylbiphenyl was determined. The title compound (Figure 1) was recrystallised before mounting it on a diffractometer. The needle like crystals undergo transformation to a smectic A phase at 326 K which finally becomes an isotropic liquid at 330.5 K.
引用
收藏
页码:45 / 50
页数:6
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