REACTION OF ORGANOLITHIUM REAGENTS WITH ETA-5-PENTADIENYL IRON COMPLEXES - FORMATION OF SIGMA,ETA-3-IRON COMPLEXES

被引：33

作者：

MCDANIEL, KF ^{[1
]}

KRACKER, LR ^{[1
]}

THAMBURAJ, PK ^{[1
]}

机构：

[1] OHIO UNIV,DEPT CHEM,ZANESVILLE,OH 43701

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)97365-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of organolithium reagents with η5-pentadienyl iron complex 4 occurs at the C2/C4 position of the π-system, generating σ,η3-iron complexes 5. Air oxidation of these σ,η3-iron complexes generates cyclohexenones. Reaction of the slightly more electron-poor η5-pentadienyl iron complex 11 gives nucleophilic attack at both the C2/C4 and the C1/C5 position. © 1990.

引用

收藏

页码：2373 / 2376

页数：4

相关论文

共 26 条

[1] THE USE OF SUPPORTED TRANSITION-METALS AND METAL-OXIDES AS CATALYSTS FOR THE METAL-CARBONYL SUBSTITUTION-REACTION [J].

ALBERS, MO ;

COVILLE, NJ ;

SINGLETON, E .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (02) :96-97

[2] IRON CARBONYL-COMPLEXES FROM VINYLCYCLOPROPANE [J].

AUMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (08) :2631-2632

[3] TRICARBONYLIRON METHOXYCYCLOHEXADIENE AND DIENYL COMPLEXES - PREPARATION, PROPERTIES AND APPLICATIONS [J].

BIRCH, AJ ;

KELLY, LF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 285 (1-3) :267-280

[4] SYNTHESIS AND REACTIVITY OF (ETA-5-C5H7)FE(PME3)3+O3SCF3- - C-C BOND FORMATION VIA NUCLEOPHILIC-ADDITION TO C2 OF AN ETA-5-PENTADIENYL LIGAND [J].

BLEEKE, JR ;

HAYS, MK .

ORGANOMETALLICS, 1987, 6 (06) :1367-1369

[5] REGIOSELECTIVE AND DIASTEREOSELECTIVE ADDITION OF METHYL ANION TO CHIRAL (PENTADIENYL)RUTHENIUM COMPLEXES [J].

BLEEKE, JR ;

RAUSCHER, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (24) :8972-8973

[6] NUCLEOPHILIC-ATTACK ON TRICARBONYL(CYCLOHEXADIENYL)OSMIUM - FORMATION OF A 6-MEMBERED SIGMA-ETA-ALLYL PRODUCT [J].

BURROWS, AL ;

JOHNSON, BFG ;

LEWIS, J ;

PARKER, DG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 194 (01) :C11-C13

[7]

CHUNG YK, 1986, J ORGANOMET CHEM, V308, P223

[8] SYNTHESIS AND ELECTROPHILIC REACTIVITY OF DICARBONYL(CYCLOHEXADIENYL)NITROSYLMANGANESE CATIONS [J].

CHUNG, YK ;

CHOI, HS ;

SWEIGART, DA ;

CONNELLY, NG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (15) :4245-4247

[9]

COTTON FA, 1971, J AM CHEM SOC, V93, P4624

[10] NUCLEOPHILIC-ADDITION TO ORGANOTRANSITION METAL-CATIONS CONTAINING UNSATURATED HYDROCARBON LIGANDS - SURVEY AND INTERPRETATION [J].

DAVIES, SG ;

GREEN, MLH ;

MINGOS, DMP .

TETRAHEDRON, 1978, 34 (20) :3047-3077