NOVEL TRIS(TRIMETHYLSILYL)METHYLBORON COMPOUNDS - CRYSTAL-STRUCTURES OF THE DIBORANE ((ME3SI)3C) HB (MU-H)2BH(C(SIME3)3) AND THE BIS(AMINOBORYL)AMINE ((ME3SI)3C(NH2)B)2NH

被引：15

作者：

ALJUAID, SS

EABORN, C

HITCHCOCK, PB

KUNDU, KK

MOLLA, ME

SMITH, JD

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)87142-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dichloroborane RBCl2 (R = (Me3Si)3C) is reduced by LiBH4 to the diborane trans-RHB(μ-H)2BHR, which melts sharply at 183-185°C. It also reacts with ammonia to give the diaminoborane RB(NH2)2 which on warming in vacuum gives the bis(aminoboryl)amine {R(NH2)B}2NH. The structures of the diborane and the bis(aminoboryl)amine have been confirmed by X-ray diffraction. © 1990.

引用

页码：13 / 21

页数：9

共 22 条

[1] TRIS(TRIMETHYLSILYL)METHYL AND TRIS(DIMETHYLPHENYLSILYL)METHYL DERIVATIVES OF BORON - CRYSTAL-STRUCTURES OF DIHYDROXY[TRIS(TRIMETHYLSILYL)METHYL]BORANE AND OF THE LITHIUM BORON COMPLEX [(MEOH)2LI(MU-OME)2B(OME)2]
ALJUAID, SS
EABORN, C
ELKHELI, MNA
HITCHCOCK, PB
LICKISS, PD
MOLLA, ME
SMITH, JD
ZORA, JA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (03): : 447 - 452
[2] THE CRYSTAL-STRUCTURE OF BIS(TRIS(TRIMETHYLSILYL)METHYL)MAGNESIUM - AN EXAMPLE OF 2-COORDINATE MAGNESIUM IN THE SOLID-STATE
ALJUAID, SS
EABORN, C
HITCHCOCK, PB
MCGEARY, CA
SMITH, JD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (05) : 273 - 274
[3] MOLECULAR-STRUCTURES OF GASEOUS (MONOMETHYLAMINO)DIMETHYLBORANE, BIS(MONOMETHYLAMINO)METHYLBORANE AND TRIS(MONOMETHYLAMINO)BORANE, (CH3)3-NB(NHCH3)N, N=1,2,3, STUDIED BY ELECTRON-DIFFRACTION
ALMENNINGEN, A
GUNDERSEN, G
MANGERUD, M
SEIP, R
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (05): : 341 - 357
[4] THE CRYSTAL AND MOLECULAR-STRUCTURE OF FLUORO(HYDROXY)[TRIS(DIMETHYLPHENYLSILYL)METHYL]BORANE
ATWOOD, JL
BOTT, SG
EABORN, C
ELKHELI, MNA
SMITH, JD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 294 (01) : 23 - 30
[5] AVENT AG, 1987, 7TH FECH C ORG CHEM, pP93
[6] ALKYLALKYLIDENEBORANES R-B=C(SIME3)2 - ISOLABLE MOLECULES WITH A 2-COORDINATED SEXTET BORON ATOM
BOESE, R
PAETZOLD, P
TAPPER, A
ZIEMBINSKI, R
[J]. CHEMISCHE BERICHTE, 1989, 122 (06) : 1057 - 1060
[7] SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF DIAMINOBORANE
BRIGGS, TS
GWINN, WD
JOLLY, WL
THORNE, LR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) : 7762 - 7763
[8] SOME STERICALLY HINDERED LITHIUM ALKYLBROMO-MAGNESATE AND ALKYLCHLORO-MAGNESATE, CADMATES, AND MANGANATES - CRYSTAL AND MOLECULAR-STRUCTURES OF [LI(THF)2(MU-BR)2MG(C(SIME3)3)(THF)], [LI(THF)4][(CD[C(SIME3)3])3(MU-BR)3(MU-3-BR)].0.5C6H12' [(LI(THF))3(MU-3-BR)3(MU-3-OSIME3)CD(C(SIME3)3)], AND [LI(THF)4][(MN[C(SIME3)3])3-(MU-CL)4(THF)] (THF = TETRAHYDROFURAN)H
BUTTRUS, NH
EABORN, C
ELKHELI, MNA
HITCHCOCK, PB
SMITH, JD
SULLIVAN, AC
TAVAKKOLI, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02): : 381 - 391
[9] PREPARATION AND CRYSTAL-STRUCTURE OF A 2-CO-ORDINATE MANGANESE COMPOUND, BIS[TRIS(TRIMETHYL)SILYLMETHYL]MANGANESE
BUTTRUS, NH
EABORN, C
HITCHCOCK, PB
SMITH, JD
SULLIVAN, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (20) : 1380 - 1381
[10] THE CRYSTAL-STRUCTURE OF THE ALKYLTRIHYDROBORATE [(THF)3LI(MU-H)3BC(SIME2PH)3], (THF = TETRAHYDROFURAN)
EABORN, C
ELKHELI, MNA
HITCHCOCK, PB
SMITH, JD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (24) : 1673 - 1674

← 1 2 3 →