THE NU(6), NU(7), NU(8), AND NU(10) BANDS OF HO2NO2

被引：11

作者：

FRIEDL, RR ^{[1
]}

MAY, RD ^{[1
]}

DUXBURY, G ^{[1
]}

机构：

[1] UNIV STRATHCLYDE,DEPT PHYS & APPL PHYS,GLASGOW G4 ONG,SCOTLAND

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1994年 / 165卷 / 02期

关键词：

D O I：

10.1006/jmsp.1994.1151

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Two new fundamental vibration-rotation bands have been observed for HO2NO2 and assigned. They are nu7 at 648 cm-1 and nu8 at 466 cm-1. On the basis of these assignments the previously observed bands at 722, 801.5, and 919 cm-1 are assigned to nu10, nu7 + nu12, and 2 nu8, respectively. A partial rotational analysis of the atmospherically relevant nu6 band has been carried out, and the effects of tunneling, Coriolis interactions, and hot bands on the rotational structure have been characterized. The band origin derived from this analysis is 802.54(3) CM-1. (C) 1994 Academic Press, Inc.

引用

页码：481 / 493

页数：13

共 22 条

[1] APPLICATION OF RRKM THEORY USING A HINDERED ROTATIONAL GORIN MODEL TSITION STATE TO REACTION HO2NO2 + N2 REVERSIBLE HO2 + NO2 + N2 [J].

BALDWIN, AC ;

GOLDEN, DM .

JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (06) :644-647

[2]

BELL W, UNPUB

[3]

BELL W, 1991, THESIS U STRATHCLYDE

[4] COMPUTER-ASSISTANCE IN THE ANALYSIS OF MOLECULAR-SPECTRA .1. ROTATIONAL STRUCTURE OF HIGH-RESOLUTION SINGLET SINGLET BANDS [J].

BIRSS, FW ;

RAMSAY, DA .

COMPUTER PHYSICS COMMUNICATIONS, 1985, 38 (01) :83-112

[5]

DUXBURY G, IN PRESS

[6] NEW SPECTRAL FEATURES OF STRATOSPHERIC TRACE GASES IDENTIFIED FROM HIGH-RESOLUTION INFRARED BALLOON-BORNE AND LABORATORY SPECTRA [J].

GOLDMAN, A ;

MURCRAY, FJ ;

BLATHERWICK, RD ;

KOSTERS, JJ ;

MURCRAY, FH ;

MURCRAY, DG .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1989, 94 (D12) :14945-14955

[7] ULTRAVIOLET AND INFRARED-ABSORPTION CROSS-SECTIONS OF GAS-PHASE HO2NO2 [J].

GRAHAM, RA ;

WINER, AM ;

PITTS, JN .

GEOPHYSICAL RESEARCH LETTERS, 1978, 5 (11) :909-911

[8] THE FOURIER-TRANSFORM INFRARED-SPECTRUM OF METHYLENEIMINE IN THE 10 MU-M REGION [J].

HALONEN, L ;

DUXBURY, G .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (05) :2078-2090

[9] A NEW VERSION OF ASYROT FOR THE HP VECTRA OR ANY IBM AT COMPATIBLE COMPUTER [J].

JUDGE, RH .

COMPUTER PHYSICS COMMUNICATIONS, 1987, 47 (2-3) :361-363

[10] PREPARATION AND THERMAL-DECOMPOSITION OF PERNITRIC ACID (HOONO2) IN AQUEOUS-MEDIA [J].

KENLEY, RA ;

TREVOR, PL ;

LAN, BY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) :2203-2206

← 1 2 3 →