NMR-STUDIES OF THE ELECTRONIC-STRUCTURE OF LOW-SPIN IRON(III) PHOSPHONITE COMPLEXES - UNUSUAL (D(XZR)D(YZ))(4)(D(XY))(1) CONFIGURATION

被引：23

作者：

GUILLEMOT, M ^{[1
]}

SIMONNEAUX, G ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM ORGANOMET & BIOL LAB,CNRS,UA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)(2)Ph}(2)]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration (d(xz),d(yz))(4) (d(xy))(1).

引用

页码：2093 / 2094

页数：2

共 17 条

[1] THE DETERMINATION OF THE PARAMAGNETIC SUSCEPTIBILITY OF SUBSTANCES IN SOLUTION BY NUCLEAR MAGNETIC RESONANCE
EVANS, DF
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1959, (JUN): : 2003 - 2005
[2] SOLUTION CHARACTERIZATION OF INTERMEDIATE-SPIN IRON(III) PORPHYRINS BY NMR-SPECTROSCOPY
GOFF, H
SHIMOMURA, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (01) : 31 - 37
[3] ORIGIN OF ANOMALOUS SORET SPECTRA OF CARBOXYCYTOCHROME P-450
HANSON, LK
EATON, WA
SLIGAR, SG
GUNSALUS, IC
GOUTERMAN, M
CONNELL, CR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) : 2672 - 2674
[4] AXIAL PERTUBATIONS ON ELECTRONIC AND MAGNETIC-PROPERTIES OF FERRIC PORPHYRINS .2. SOLVENT EFFECTS ON PROTON NMR-SPECTRA OF LOW-SPIN CYANO COMPLEXES
LAMAR, GN
DELGAUDIO, J
FRYE, JS
[J]. BIOCHIMICA ET BIOPHYSICA ACTA, 1977, 498 (02) : 422 - 435
[5] AXIAL PERTURBATIONS ON ELECTRONIC AND MAGNETIC-PROPERTIES OF FERRIC PORPHYRINS .1. EFFECTS OF AXIAL LIGAND BASICITY IN BIS-SUBSTITUTED PYRIDINE COMPLEXES OF SYNTHETIC PORPHYRINS
LAMAR, GN
BOLD, TJ
SATTERLEE, JD
[J]. BIOCHIMICA ET BIOPHYSICA ACTA, 1977, 498 (01) : 189 - 207
[6] LAMAR GN, 1977, J BIOINORG CHEM, V2, P207
[7] PREPARATION AND CHARACTERIZATION OF LOW-SPIN IRON(II) PORPHYRIN COMPLEXES WITH BIS(PHOSPHINE) OR BIS(PHOSPHITE) AXIAL LIGANDS
OHYA, T
MOROHOSHI, H
SATO, M
[J]. INORGANIC CHEMISTRY, 1984, 23 (09) : 1303 - 1305
[8] MISSING HEME SPIN STATE AND A MODEL FOR CYTOCHROME C' - MIXED S = (3/2, 5/2) INTERMEDIATE SPIN FERRIC PORPHYRIN - PERCHLORATO(MESO-TETRAPHENYLPORPHINATO)IRON(III)
REED, CA
MASHIKO, T
BENTLEY, SP
KASTNER, ME
SCHEIDT, WR
SPARTALIAN, K
LANG, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (11) : 2948 - 2958
[9] HYPERPORPHYRIN SPECTRA OF FERRIC DIMERCAPTIDE HEMIN COMPLEXES - MODELS FOR FERRIC CYTOCHROME P450-THIOL COMPLEXES
RUF, HH
WENDE, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (16) : 5499 - 5500
[10] MODELS FOR FERRIC CYTOCHROME-P450 - CHARACTERIZATION OF HEMIN MERCAPTIDE COMPLEXES BY ELECTRONIC AND ESR-SPECTRA
RUF, HH
WENDE, P
ULLRICH, V
[J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 1979, 11 (03) : 189 - 204

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