FE4(CO)12(MU4-RP) - A TRIPLE-DECKER DERIVATIVE OF THE 2PI-LIGAND RPFE2(CO)6

被引:9
作者
BUCHHOLZ, D [1 ]
HUTTNER, G [1 ]
IMHOF, W [1 ]
ORAMA, O [1 ]
机构
[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY
关键词
D O I
10.1016/0022-328X(90)85379-D
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of Fe3(CO)10(μ3-iPrP) with KOCN and Et3OBF4 gives Fe4(CO)12(μ-RP) as a byproduct. Its structure with a basic trigonal-bipyramidal architecture and the RP-fragment in an equatorial position warrants its description as a tripledecker derivative of the organometallic 2π-ligand RPFe2(CO)6. © 1990.
引用
收藏
页码:321 / 325
页数:5
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