OXOVANADIUM-INDUCED OXIDATIVE DESILYLATION FOR THE SELECTIVE SYNTHESIS OF 1,4-DIKETONES

被引：71

作者：

FUJII, T ^{[1
]}

HIRAO, T ^{[1
]}

OHSHIRO, Y ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

关键词：

D O I：

10.1016/0040-4039(92)89041-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Silyl enol ethers underwent the VO(OR)Cl2-induced homo- or cross-coupling giving 1,4-diketones selectively via one-electron oxidative desilylation.

引用

页码：5823 / 5826

页数：4

共 6 条

[1]

BACIOCCHI E, 1990, SYNLETT, P679

[2]

FUKUZUMI S, UNPUB

[3] VO(OR)CL2-INDUCED CYCLIZATION OF DIKETENE VIA RING-OPENING [J].

HIRAO, T ;

FUJII, T ;

OHSHIRO, Y .

HIRAO, T ;

FUJII, T ;

MIYATA, S ;

OHSHIRO, Y .

ITO, Y ;

KONOIKE, T ;

SAEGUSA, T .

[6]

KOBAYASHI Y, 1980, CHEM PHARM BULL, V28, P262