HIGHLY REGIOSELECTIVE AND STEREOSELECTIVE ANNULATION ELIMINATION-REACTIONS OF 1-CYCLOALKENYL 3-HYDROXYPROPYL ETHERS

被引：10

作者：

ISHIHARA, K ^{[1
]}

HANAKI, N ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] NAGOYA UNIV,SCH ENGN,NAGOYA,AICHI 46401,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly regio- and stereo-selective annulation-elimination reactions of 1-cycloalkenyl 3-hydroxypropyl ethers in the presence of triflic anhydride and tertiary amines are described; the bicyclic vinyl ethers produced are converted to 2-substituted delta-lactones, macrocyclic oxolactones and bicyclic hydroxy ethers by ozonolysis and stereoselective hydroboration.

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页码：1117 / 1118

页数：2

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