GROUP-TRANSFER POLYMERIZATION OF BENZYL METHACRYLATE - A CONVENIENT METHOD FOR SYNTHESIS OF NEAR-MONODISPERSE POLY(METHACRYLIC ACID)S

被引：33

作者：

MYKYTIUK, J ^{[1
]}

ARMES, SP ^{[1
]}

BILLINGHAM, NC ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

POLYMER BULLETIN | 1992年 / 29卷 / 1-2期

关键词：

D O I：

10.1007/BF00558048

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Group-transfer polymerization of benzyl methacrylate has been shown to proceed smoothly to give polymers of low (M(w)BAR/M(n)BAR < 1.1) polydispersity, with good control of molecular weight. Removal of the benzyl groups can be achieved easily via catalytic hydrogenation at room temperature and takes place without main chain scission. This is thus a very effective route for the synthesis of monodisperse poly(methacrylic acid)s.

引用

页码：139 / 145

页数：7

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