SYNTHESIS, CHARACTERIZATION AND PHYSICOCHEMICAL STUDIES OF WEAKLY INTERACTING REDOX-RESPONSIVE BINUCLEAR COMPLEXES INCORPORATING ETHYLENEDIAMINETETRAACETATORUTHANATE(III)

被引：14

作者：

DAS, A

BAJAJ, HC

CHATTERJEE, D

机构：

[1] Discipline of Coordination Chemistry, Central Salt and Marine Chemicals Research Institute, Bhavnagar

来源：

POLYHEDRON | 1995年 / 14卷 / 23-24期

关键词：

D O I：

10.1016/0277-5387(95)00171-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel binuclear complexes of the type [{Ru(edtaH)}(2)L] [edta = ethylenediaminetetraacetate, L = pyrazine, 4,4'-bipyridyl, 3,3'-dimethyl-4,4'-bipyridyl, trans-1,2-bis(4-pyridyl)ethylene] have been synthesized and characterized by physicochemical methods. All the complexes showed weak metal-metal interaction, depending on the nature of the bridging ligand, L. The electrochemical and magnetic susceptibility measurements are consistent with weak interactions between the ruthenium centres.

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页码：3585 / 3589

页数：5

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