ADDITION-REACTION OF BENZYNE TO C60

被引：44

作者：

TSUDA, M ^{[1
]}

ISHIDA, T ^{[1
]}

NOGAMI, T ^{[1
]}

KURONO, S ^{[1
]}

OHASHI, M ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN, DEPT APPL PHYS & CHEM, CHOFU, TOKYO 182, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 12期

关键词：

D O I：

10.1246/cl.1992.2333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzyne generated by the reaction of 2-aminobenzoic acid and pentyl nitrite in a refluxing benzene was found to add to C60 in good yield, The reaction products were separated by HPLC to give C60(C6H4), C60(C6H4)2, C60(C6H4)3, and C60(C6H4)4, which were confirmed by mass spectra. H-1 NMR spectrum of C60(C6H4) is consistent with the structure of mono-addition product, whereas those of C60(C6H4)2, C60(C6H4)3, and C60(C6H4)4 indicate that they consist of the corresponding mixtures of isomers.

引用

页码：2333 / 2334

页数：2

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