CRYSTAL AND MOLECULAR-STRUCTURE OF A METASTABLE MODIFICATION OF PHOSPHORUS-PENTACHLORIDE

被引：8

作者：

FINCH, A

FITCH, AN

GATES, PN

机构：

[1] UNIV LONDON ROYAL HOLLOWAY & BEDFORD NEW COLL,DEPT CHEM,EGHAM TW20 0EX,SURREY,ENGLAND

[2] UNIV KEELE,DEPT CHEM,KEELE ST5 5BG,STAFFS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High resolution powder X-ray diffraction using synchrotron radiation has established the formulation PCl4+]2[PCl6-][Cl-] for a metastable form of PCl5 with significant interaction between the PCl4+ and Cl- ions.

引用

页码：957 / 958

页数：2

共 10 条

[1] 134 the crystal structure of phosphorus pentachloride [J].

Clark, D ;

Powell, HM ;

Wells, AF .

JOURNAL OF THE CHEMICAL SOCIETY, 1942, :642-645

[2]

COCKCROFT JK, 1990, RIETVELD REFINEMENT

[3] SINGLE-HALIDE ANIONS IN PHOSPHORUS(V) HALIDE-COMPLEXES - A RAMAN INVESTIGATION [J].

FINCH, A ;

GATES, PN ;

MUIR, AS .

POLYHEDRON, 1986, 5 (10) :1537-1542

[4] STUDIES ON THE CHEMISTRY OF HALOGENS AND OF POLYHALIDES .7. THE ADDITION OF BROMINE TO PHOSPHORUS TRICHLORIDE [J].

POPOV, AI ;

GESKE, DH ;

BAENZIGER, NC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (09) :1793-1796

[5] Crystal structure of phosphorus pentachloride [J].

Powell, HM ;

Clark, D ;

Wells, AF .

NATURE, 1940, 145 :149-149

[6]

POWELL HM, 1940, NATURE, V145, P1971

[7] STRUCTURAL REFINING AND STUDY OF THERMAL VIBRATIONS ON SOLID PHOSPHORUS(V) CHLORIDE [J].

PREISS, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 380 (01) :51-&

[8] A PROFILE REFINEMENT METHOD FOR NUCLEAR AND MAGNETIC STRUCTURES [J].

RIETVELD, HM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1969, 2 :65-&

[9]

Van Driel M, 1941, RECL TRAV CHIM PAY-B, V60, P869

[10] A FULLY AUTOMATIC PROGRAM FOR FINDING UNIT CELL FROM POWDER DATA [J].

VISSER, JW .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1969, 2 :89-&

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