TRANSITION-METAL POLYHYDRIDES-CATALYZED ADDITION OF ACTIVATED NITRILES TO ALDEHYDES AND KETONES VIA KNOEVENAGEL CONDENSATION

被引：38

作者：

LIN, YR

ZHU, XC

XIANG, M

机构：

[1] Laboratary of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, 200032 Shanghai

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 448卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80087-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Transition metal polyhydrides and dihydrogen complexes catalyze Knoevenagel addition of cyanoacetate to aldehydes and ketones under neutral and mild conditions, the adducts undergo dehydration to give substituted (E)-2-cyano-alpha,beta-unsaturated esters exclusively.

引用

页码：215 / 218

页数：4

共 18 条

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