NOVEL REACTIONS OF THE [BPH4]- SALT OF THE BIFUNCTIONAL COMPLEX [(MEC[CH2PPH2]3)RH(S2CO)]+ MEC[CH2PPH2]3 - ONE-ELECTRON REDUCTION, CLEAVAGE OF B-H AND B-C BONDS, AND METATHESIS OF CS2-LIKE HETEROALLENE MOLECULES

被引：29

作者：

BIANCHINI, C ^{[1
]}

MELI, A ^{[1
]}

LASCHI, F ^{[1
]}

VIZZA, F ^{[1
]}

ZANELLO, P ^{[1
]}

机构：

[1] UNIV SIENA,DEPARTIMENTO CHEM,I-53100 SIENA,ITALY

来源：

INORGANIC CHEMISTRY | 1989年 / 28卷 / 02期

关键词：

D O I：

10.1021/ic00301a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：227 / 233

页数：7

共 38 条

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[3] COMPREHENSIVE EXPERIMENTAL AND INTERPRETATIONAL STUDY OF THE COMPLEX-FORMATION AND TRANSFORMATIONS INVOLVING ORTHO-QUINOID MOLECULES AND AN L3COBALT-TYPE METAL FRAGMENT
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[4] STEPWISE METAL-PROMOTED CONVERSION OF NU-2-CS2 INTO NU-2-SO - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE COMPLEX [(TRIPHOS)RH(MU-SO)2RH(TRIPHOS)][BPH4]2.HCONME2 [TRIPHOS = MEC(CH2PPH2)3]
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[6] CHEMICAL AND ELECTROCHEMICAL OXIDATION OF THE PHOSPHONIODICHALCOGENOFORMATE COMPLEXES (TRIPHOS)RHCL(X2CPET3) (TRIPHOS = MEC(CH2PPH2)3, X = S, SE) - SYNTHESIS OF METAL DICHALCOGENOCARBONATES FROM O-2 AND PHOSPHONIUM-BETAINE-LIKE COMPLEXES - X-RAY STRUCTURE OF [(TRIPHOS)RH(S2CH(PET3))](BPH4)2
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[7] STEPWISE METAL-ASSISTED CONVERSION OF ETA-2-CSE2 TO ETA-1-SE2CPET3, ETA-2-SE2CO, AND ETA-2-SE2 - CRYSTAL-STRUCTURES OF THE COMPLEXES [MEC(CH2PPH2)3)RH(SE2CO)]BPH4.0.5CH2CL2.0.5C4H9OH AND [(MEC(CH2PPH2)3)RH(MU-SE2)2RH(MEC(CH2PPH2)3](BPH4)2.2DMF
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[8] METAL-ASSISTED 3-FRAGMENT DEMOLITION OF THE DITHIOCARBONATE LIGAND - A NEW SYNTHETIC ROUTE TO HOMOBINUCLEAR AND HETEROBINUCLEAR BIS(MU-SULFIDO)METAL COMPLEXES - CHEMICAL, ELECTROCHEMICAL, AND SPECTROSCOPIC CHARACTERIZATION OF A FAMILY OF COMPLEXES OF IRON, COBALT, RHODIUM, AND PLATINUM WITH BRIDGING SULFIDO LIGANDST
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[9] CHEMISTRY OF ET3P.CS2 METAL-COMPLEXES - SYNTHESIS OF 1,1-DITHIOLATE COMPLEXES VIA NUCLEOPHILIC ATTACKS ON [(TRIPHOS)CO(S2CPET3)](BPH4)2 - X-RAY STRUCTURE OF [(TRIPHOS)CO(S2CO)]
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[J]. INORGANIC CHEMISTRY, 1982, 21 (12) : 4166 - 4169
[10] STRUCTURAL COMPARISON OF COBALT AND NICKEL-COMPLEXES WITH CS2 AND SCNPH MOLECULES STABILIZED BY TRIPODAL POLYPHOSPHINE LIGANDS - IMPLICATIONS FOR THE NATURE OF THE CHEMICAL BONDING IN COMPOUNDS CONTAINING C-S LINKAGES ETA-2 COORDINATED TO L3M FRAGMENTS
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