SYNTHESIS, STRUCTURE AND REACTIVITY OF CATIONIC RHODIUM(I) AND IRIDIUM(I) THIOETHER CROWNS - STRUCTURES OF [M([9]ANES3)(COD)]+ (M = RH, IR, COD = CYCLOOCTA-1,5-DIENE) AND [RH([9]ANES3)(C2H4)2]+ ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE)

被引：39

作者：

BLAKE, AJ ^{[1
]}

HALCROW, MA ^{[1
]}

SCHRODER, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/C39910000253

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Reaction of M1 species with [9]aneS3 affords half-sandwich complexes including [M([9]aneS3)(cod)]+, [M([9]aneS3)(coe)2]+ (M = Rh, lr; coe = cyclooctene), [(Rh([9]aneS3)(C2H4)2]+, [Rh([9]aneS3)(C2H4)(PR3)]+ (R = Ph, cyclohexyl), [Rh([9]aneS3)(CO)(PPh3)]+ and [Rh([9]aneS3)(tcne)?? (NCMe)]+; crystal structure determinations of [M([9]aneS3)(cod)]+ (M = Rh, lr) and [Rh([9]aneS3)(C2H4)2]+ confirm these complexes to be five-coordinate, and the latter species reacts with C-X (X = halide) bonds.

引用

页码：253 / 256

页数：4

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