MOLECULAR-ORBITAL CALCULATIONS RELEVANT TO THE HYPER-CLOSO VS ISO-CLOSO CONTROVERSY IN METALLABORANES

被引：100

作者：

JOHNSTON, RL ^{[1
]}

MINGOS, DMP ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

INORGANIC CHEMISTRY | 1986年 / 25卷 / 18期

关键词：

D O I：

10.1021/ic00238a043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：3321 / 3323

页数：3

共 15 条

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[2] CLOSO-CARBAMETALLOBORANES WITH METAL-HYDROGEN BONDS FROM DIRECT INSERTION INTO ARACHNO-CARBABORANES - THE MOLECULAR-STRUCTURES OF [2-H-2,2-(ET3P)2-1,6,2-C2COB7H9] AND [2-H-2,2-(ET3P)2-1,6,2-C2RHB7H9] AND A MOST UNUSUAL CRYSTALLOGRAPHIC COINCIDENCE [J].

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[3] FACILE THERMALLY-INDUCED CLUSTER OXIDATIONS IN METALLABORANE CHEMISTRY - ARACHNO-]NIDO-]CLOSO REACTION SEQUENCES EXHIBITED BY IRIDANONABORANES AND IRIDADECABORANES, AND THE STABILIZATION OF THE IRIDIUM(V) OXIDATION-STATE [J].

BOULD, J ;

CROOK, JE ;

GREENWOOD, NN ;

KENNEDY, JD ;

MCDONALD, WS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (06) :346-348

[4] QUANTITATIVE ORTHO-CYCLOBORONATION OF P-PHENYL GROUPS IN METALLABORANE CHEMISTRY AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE NOVEL ISO-CLOSO-TEN-VERTEX METALLABORANE [1,1,1-H(PPH3)(PH2P-ORTHO-C6H4)-ISO-CLOSO-(1-IRB9H8-2-) [J].

BOULD, J ;

GREENWOOD, NN ;

KENNEDY, JD ;

MCDONALD, WS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (08) :465-467

[5] THE PAIRING PRINCIPLE IN TENSOR SURFACE HARMONIC THEORY - ELECTRON COUNTS OF LARGE CLOSO BORANES [J].

FOWLER, PW .

POLYHEDRON, 1985, 4 (12) :2051-2057

[6] METALLOBORANE CLUSTER COMPOUNDS [J].

GREENWOOD, NN .

PURE AND APPLIED CHEMISTRY, 1983, 55 (01) :77-87

[7] METALLOBORANES 1983 [J].

GREENWOOD, NN .

PURE AND APPLIED CHEMISTRY, 1983, 55 (09) :1415-1430

[8] OVERLAP CONTROL AND STABILITY OF POLYHEDRAL MOLECULES - CLOSO-CARBORANES [J].

JEMMIS, ED .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7017-7020

[9] STRUCTURE AND BONDING IN SOME RECENTLY ISOLATED METALLABORANES [J].

KENNEDY, JD .

INORGANIC CHEMISTRY, 1986, 25 (01) :111-112

[10] POLYHEDRAL SKELETAL ELECTRON PAIR APPROACH [J].

MINGOS, DMP .

ACCOUNTS OF CHEMICAL RESEARCH, 1984, 17 (09) :311-319

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