THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW POLYOXOVANDIUM CLUSTER ANION - [ASIII8VIV14O42(0.5H2O)]4-

被引：91

作者：

HUAN, G

GREANEY, MA

JACOBSON, AJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000260

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dark-brown compound [N(Me)4]4[As(III)8V(IV)14O42(0.5H2O)], containing a spherical anion [As(III)8V(IV)O14(42)(0.5H2O)]4-containing condensed VO5 square pyramids and As2O5 units, is synthesized hydrothermally from As2O3, V2O5 and (Me)4NOH and structurally characterized by X-ray diffraction.

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页码：260 / 261

页数：2

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