NEW CERIUM NITRIDE CHLORIDES - CE6CL12N2 AND CENCL

被引：22

作者：

EHRLICH, GM

BADDING, ME

BRESE, NE

TRAIL, SS

DISALVO, FJ

机构：

[1] Department of Chemistry, Cornell University, Ithaca

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 206卷 / 01期

关键词：

Chlorine compounds - Crystal structure - Synthesis (chemical) - X ray analysis;

D O I：

10.1016/0925-8388(94)90015-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The compound CeNCl is shown to be isotypic with tetragonal BiOCl with lattice parameters a = b = 4.079(2) angstrom, c = 6.837(2) angstrom. The compound Ce6Cl12N2 was prepared from CeCl3, Ce and NaN3 in a sealed Nb tube at 750-degrees-C. The structure of Ce6Cl12N2 was solved by X-ray single crystal diffraction and shown to contain edge-shared, nitrogen-centered, cerium tetrahedra. The lattice parameters for Ce6Cl12N2 were determined to be a = 11.233(4) angstrom, b = 16.527(8) angstrom, c = 10.708(3) angstrom, beta = 90.15-degrees in the spacegroup P2(1)/c.

引用

页码：95 / 101

页数：7

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