BINUCLEAR AND POLYMERIC MANGANESE(II) SALICYLATE COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURE AND CATALYTIC ACTIVITY OF [MN-2(HSAL)(4)(H2O)(4)] AND [(MN-2(SAL)(2)(HSAL)(H2O)-(H3O)(PY)(4)CENTER-DOT-2PY)(N)](H(2)SAL=SALICYLIC ACID, PY=PYRIDINE)

被引：46

作者：

DEVEREUX, M

MCCANN, M

CASEY, MT

CURRAN, M

FERGUSON, G

CARDIN, C

CONVERY, M

QUILLET, V

机构：

[1] ST PATRICKS COLL, DEPT CHEM, MAYNOOTH, KILDARE, IRELAND

[2] UNIV GUELPH, DEPT CHEM & BIOCHEM, GUELPH, ON N1G 2W1, CANADA

[3] UNIV READING, DEPT CHEM, READING RG6 2AD, BERKS, ENGLAND

[4] UNIV LEEDS, DEPT BIOCHEM & MOLEC BIOL, LEEDS LS2 9JT, W YORKSHIRE, ENGLAND

[5] UNIV DUBLIN TRINITY COLL, DUBLIN 2, IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 05期

关键词：

D O I：

10.1039/dt9950000771

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The two air-stable manganese(II) salicylate complexes [Mn-2(Hsal)(4)(H2O)(4)] 1 and polymeric [{Mn-2(sal)(2)(Hsal)(H2O)(H3O)(py)(4).2py}(n)] 2 (H(2)sal = salicylic acid and py = pyridine) have been synthesised easily, and their crystal structures determined. Both contain unsymmetrically bridging salicylate ligands. In the presence of added pyridine 1 and 2 vigorously catalyse the disproportionation of H2O2.

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页码：771 / 776

页数：6

相关论文

共 20 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2] CATALASE MODELING .2. DYNAMICS OF REACTION OF A WATER-SOLUBLE AND NON-MU-OXO DIMER FORMING MANGANESE(III) PORPHYRIN WITH HYDROGEN-PEROXIDE [J].

BALASUBRAMANIAN, PN ;

SCHMIDT, ES ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (25) :7865-7873

[3] TETRANUCLEAR MANGANESE(III)-OXO CARBOXYLATE COMPLEXES POSSESSING TERMINAL PHENOXIDE OR ALKOXIDE LIGANDS [J].

BOUWMAN, E ;

BOLCAR, MA ;

LIBBY, E ;

HUFFMAN, JC ;

FOLTING, K ;

CHRISTOU, G .

INORGANIC CHEMISTRY, 1992, 31 (25) :5185-5192

[4] SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A DINUCLEAR MANGANESE(II) COMPLEX WITH ONE MU-AQUA AND 2 MU-CARBOXYLATO BRIDGES [J].

CANESCHI, A ;

FERRARO, F ;

GATTESCHI, D ;

MELANDRI, MC ;

REY, P ;

SESSOLI, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10) :1365-1367

[5] SYNTHESIS AND STRUCTURE OF THE MN-II,MN-II COMPLEX SALT [MN-2(ETA(1)ETA(1)MU(2)-ODA)(PHEN)(4)(H2O)(2)][MN-2(ETA(1)ETA(1)MU(2)-ODA)(PHEN)(4)(ETA(1)-ODA)(2)]CENTER-DOT-4H2O (ODAH(2)=OCTANEDIOIC ACID) - A CATALYST FOR H2O2 DISPROPORTIONATION [J].

CASEY, MT ;

MCCANN, M ;

DEVEREUX, M ;

CURRAN, M ;

CARDIN, C ;

CONVERY, M ;

QUILLET, V ;

HARDING, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (22) :2643-2645

[6] NONANUCLEAR OXIDE-BRIDGED MANGANESE COMPLEX - PREPARATION, STRUCTURE, AND MAGNETIC-PROPERTIES OF [MN9O4(O2CPH)8(SAL)4(SALH)2(PYR)4] (SALH2 = SALICYCLIC ACID, PYR = PYRIDINE) [J].

CHRISTMAS, C ;

VINCENT, JB ;

CHANG, HR ;

HUFFMAN, JC ;

CHRISTOU, G ;

HENDRICKSON, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (03) :823-830

[7]

COTTON FA, 1988, ADV INORG CHEM RAD, P702

[8]

FLAIG W, 1975, SOIL COMPONENTS, V1, P1

[9] NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].

GABE, EJ ;

LEPAGE, Y ;

CHARLAND, JP ;

LEE, FL ;

WHITE, PS .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 :384-387

[10] THE PEROXIDE-DEPENDENT MU-2-O BOND FORMATION OF [MN(IV)SALPN(O)]2 [J].

LARSON, EJ ;

PECORARO, VL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (10) :3810-3818