DIACETONE GLUCOSE ARCHITECTURE AS A CHIRALITY TEMPLATE .1. CRUCIAL EFFECTS OF THE INTRAMOLECULAR OXYGENS UPON THE LIALH4 REDUCTION OF THE PROPARGYL ALCOHOL OF 3-C-ETHYNYL-1,2-5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-ALLOFURANOSE DERIVATIVES

被引：8

作者：

KAKINUMA, K

MATSUZAWA, T

EGUCHI, T

机构：

[1] Department of Chemistry, Tokyo Institute of Technology O-okayama, Meguro-ku, Tokyo

来源：

TETRAHEDRON | 1991年 / 47卷 / 34期

关键词：

LIALH4 REDUCTION OF PROPARGYL ALCOHOL; REGIOCHEMISTRY; REACTIVITY; SEMIEMPIRICAL MO CALCULATION; DIACETONE GLUCOSE;

D O I：

10.1016/S0040-4020(01)96152-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The facile as well as regio- and stereoselective reactivity of 3-C-ethynl-1,2:5,6-di-O-isopropylidene-alpha-D-allofuranose derivatives for LiAlH4 reduction into the corresponding ethenyl derivatives were investigated. The effect of oxygen atoms on the reduction is discussed by means of semi-empirical MO calculation.

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页码：6975 / 6982

页数：8

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