DESULFURIZATION AND C-C COUPLING IN THE REACTION OF THE ANIONS [MNM(CO)6(MU-H)(MU-S2CPCY3)]-(M=MN,RE) WITH CARBON-DISULFIDE - X-RAY STRUCTURE OF [LI(THF)3][MN2(CO)6(MU-H)(MU-S(S)C=C(PCY3)S)]

被引：13

作者：

ALVAREZ, B

GARCIAGRANDA, S

LI, J

MIGUEL, D

RIERA, V

机构：

[1] UNIV OVIEDO,DEPT QUIM ORGANOMETAL,E-33071 OVIEDO,SPAIN

[2] UNIV OVIEDO,DEPT QUIM FIS & ANAL,E-33071 OVIEDO,SPAIN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 01期

关键词：

D O I：

10.1021/om00013a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anions [MnM(CO)6(mu-H)(mu-S2CPCY3)]-(M = Mn, Re) react with CS2 to afford the new anionic species [MnM(CO)6(mu-H){mu-S(S)C=C(PCY3)S}]-, containing the new (tricyclohexylphosphonio)ethenetrithiolate ligand S(S)C=C(PCY3)S. This results from a complex pathway which involves formally the desulfurization Of CS2 and the insertion of CS into a C-S bond of the S2CPCy3 ligand on the parent anion, with formation of a carbon-carbon double bond.

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页码：16 / 17

页数：2

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