RAMAN-STUDY OF THE BENDING BAND OF WATER

被引：20

作者：

PAVLOVIC, M ^{[1
]}

BARANOVIC, G ^{[1
]}

LOVREKOVIC, D ^{[1
]}

机构：

[1] RUDJER BOSKOVIC INST, POB 1016, YU-41001 Zagreb, Croatia, YUGOSLAVIA

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 07期

关键词：

D O I：

10.1016/0584-8539(91)80277-P

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectra of ordinary and isotopic water in the region of the deformation mode have been studied. The isotropic and anisotropic Raman components were analysed by the method of Fourier self-deconvolution, resolution enhancement using polarization data and numerical band fitting. The choice of different profiles and their number have been discussed. The obtained resolution of the isotropic component into two profiles of comparable intensities and of the anisotropic component into two profiles whose intensities differ by 5-10 times supports the existence of the two structures in liquid water of strongly and weakly hydrogen-bonded oscillators with appreciable difference in their depolarization ratios.

引用

页码：897 / 906

页数：10

共 23 条

[1] EFFECTS OF HYDROGEN-BONDING ON THE RAMAN INTENSITIES OF METHANOL, ETHANOL AND WATER [J].

ABE, N ;

ITO, M .

JOURNAL OF RAMAN SPECTROSCOPY, 1978, 7 (03) :161-167

[2] RAMAN SCATTERING - ORIENTATIONAL MOTIONS IN LIQUIDS [J].

BARTOLI, FJ ;

LITOVITZ, TA .

JOURNAL OF CHEMICAL PHYSICS, 1972, 56 (01) :413-&

[3] CONNECTIVITY OF HYDROGEN-BONDS IN LIQUID WATER [J].

BLUMBERG, RL ;

STANLEY, HE ;

GEIGER, A ;

MAUSBACH, P .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (10) :5230-5241

[4]

CLARKE JHR, 1978, ADV INFRARED RAMAN S, V4, P109

[5] FLUCTUATION HYPOTHESIS OF HYDROGEN-BONDING .6. CALCULATION OF BAND SHAPES IN INFRA-RED AND RAMAN-SPECTRA FOR NORMAL AND HEAVY-WATER IN REGION OF STRETCHING VIBRATIONS [J].

EFIMOV, YY ;

NABERUKHIN, YI .

MOLECULAR PHYSICS, 1978, 36 (04) :973-992

[6] FREQUENCIES OF H-O-H, H-O-D AND D-O-D BENDING FUNDAMENTALS IN LIQUID WATER [J].

FALK, M .

JOURNAL OF RAMAN SPECTROSCOPY, 1990, 21 (09) :563-567

[7] TEMPERATURE EVOLUTION OF SINGLE-PARTICLE CORRELATION-FUNCTIONS OF LIQUID WATER [J].

FRATTINI, R ;

RICCI, MA ;

RUOCCO, G ;

SAMPOLI, M .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (04) :2540-2547

[8] CONCENTRATION-DEPENDENCE STUDIES OF RAMAN-SPECTRA OF WATER BY THE METHOD OF SELF-DECONVOLUTION [J].

GEORGIEV, GM ;

KALKANJIEV, TK ;

PETROV, VP ;

NICKOLOV, Z ;

MITEVA, M .

CHEMICAL PHYSICS LETTERS, 1983, 103 (01) :83-88

[9] NEUTRON-DIFFRACTION STUDIES OF WATER .3. STRUCTURAL-CHANGE AS A FUNCTION OF TEMPERATURE [J].

GIBSON, IP ;

DORE, JC .

MOLECULAR PHYSICS, 1983, 48 (05) :1019-1030

[10] THE BIFURCATED HYDROGEN-BOND MODEL OF WATER AND AMORPHOUS ICE [J].

GIGUERE, PA .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (08) :4835-4839

← 1 2 3 →