REDOX, FRAGMENTATION AND CLUSTERING PROCESSES IN THE EXCITATION OF METAL-COMPLEXES BY FAST-ATOM-BOMBARDMENT - RELATIONSHIPS WITH PHOTOCHEMICAL PATHWAYS

被引：7

作者：

KEMP, TJ

机构：

[1] Department of Chemistry, University of Warwick, Coventry

来源：

COORDINATION CHEMISTRY REVIEWS | 1993年 / 125卷 / 1-2期

关键词：

D O I：

10.1016/0010-8545(93)85029-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Comparison is made between the variety of primary processes undergone by complexes of the transition metals on photochemical excitation in solution and those induced by fast atom bombardment (FAB) in a matrix of an involatile liquid. All of the well-established photochemical pathways (redox, dissociation, association, solvolysis, ligand fragmentation and clustering) have a counterpart in FAB, although the extent to which they occur can differ markedly.

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页码：333 / 350

页数：18

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