LASER EXCITATION AND RESOLVED EMISSION-SPECTRA OF SUPERSONICALLY COOLED ALUMINUM DIMER

被引：14

作者：

CAI, MF ^{[1
]}

CARTER, CC ^{[1
]}

MILLER, TA ^{[1
]}

BONDYBEY, VE ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST PHYS CHEM,W-8046 GARCHING,GERMANY

来源：

CHEMICAL PHYSICS | 1991年 / 155卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0301-0104(91)87023-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The laser induced fluorescence excitation spectra of the E 3-SIGMA-g-X 3-PI-u, F 3-SIGMA-g-X 3-PI-u, and G 3-PI-g-X 3-PI-u transitions of Al2 have been recorded. Rotationally resolved spectra have been obtained for the F 3-SIGMA-g-X 3-PI-u and G 3-PI-g-X 3-PI-u transitions. In the latter case, a detailed rotational analysis allows the determination of the rotational and spin-orbit coupling constants of both states. Some additional observations concerning both the radiative and non-radiative decay pathways for these excited states are reported.

引用

页码：233 / 245

页数：13

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