METAL-PI-COMPLEXES OF HETEROARENES .3. BIS(ETA-6-PHOSPHABENZENE)VANADIUM - SYNTHESIS, STRUCTURE, REDOX PROPERTIES, AND CONFORMATIONAL FLEXIBILITY

被引：65

作者：

ELSCHENBROICH, C

NOWOTNY, M

METZ, B

MASSA, W

GRAULICH, J

BIEHLER, K

SAUER, W

机构：

[1] Fachbereich Chemie, Universität Marburg, W-3550, Hans-Meerwein-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期

关键词：

D O I：

10.1002/anie.199105471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-ligand condensation was used to prepare the first binary heteroarene complex of a group 15 metal, bis(eta-6-phosphabenzene)-vanadium (1). It was fully characterized by EPR spectroscopy, X-ray structure analysis, and cyclovoltammetry. In contrast to the free ligand and to the analogous benzene complex, 1 is thermally stable and is very stable toward oxidizing agents.

引用

页码：547 / 550

页数：4

共 28 条

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