DEVELOPMENT OF A SURFACE-ACOUSTIC-WAVE GAS SENSOR FOR ORGANOSPHOSPHORUS NERVE AGENTS EMPLOYING LANTHANIDE COMPOUNDS AS THE CHEMICAL INTERFACE

被引:22
作者
NIEUWENHUIZEN, MS
HARTEVELD, JLN
机构
[1] TNO Prins Maurits Laboratory, 2280 AA Rijswijk
关键词
D O I
10.1016/0039-9140(94)80153-3
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The results of a study dealing with surface acoustic wave gas sensors for organophosphorus compounds such as nerve agents are described. Several lanthanum coordination compounds were applied as the chemical interface. The various sensors prepared were challenged with both the nerve agent sarin and the simulant dimethyl methylphosphonate. Many aspects were studied. such as sensitivity, selectivity. reversibility and response rate as well as the effect of temperature and structural features. Detection limits down to 0.1 ppm were found. Response rates require further improvement. Degradation phenomena were observed which in some cases yielded irreversible responses. The selectivity for organophosphorus compounds was found to be promising.
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收藏
页码:461 / 472
页数:12
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