DIRECT CONVERSION OF ETHANE TO ETHANOL BY THE HOMOGENEOUS PARTIAL OXIDATION AT HIGH-PRESSURES

被引：10

作者：

GESSER, HD

HUNTER, NR

MORTON, LA

YARLAGADDA, PS

机构：

[1] Chemistry Department, University of Manitoba, Winnipeg, MB

来源：

ENERGY & FUELS | 1991年 / 5卷 / 03期

关键词：

D O I：

10.1021/ef00027a011

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The results of the homogeneous high-pressure (10-100 atm) oxidation of ethane to ethanol are reported. The products identified and analyzed were ethanol, methanol, acetaldehyde, methane, carbon monoxide, carbon dioxide, and water. The highest value of the ratio ethanol/methanol in the products was 6, obtained at the highest pressure studied (100 atm). A mechanism is proposed to account for the products.

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页码：423 / 427

页数：5

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