MORPHOLOGICAL-STUDIES ON THE BLENDS OF POLY(BUTYLENE TEREPHTHALATE) AND BISPHENOL-A POLYCARBONATE

被引:37
作者
HALDER, RS
JOSHI, M
MISRA, A
机构
[1] Center for Materials Science and Technology, Indian Institute of Technology, Delhi, New Delhi
关键词
D O I
10.1002/app.1990.070390604
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The morphology of the blends of poly(butylene terephthalate) (PBT) and bisphenol‐A polycarbonate (PC) crystallized from the melt were studied by density measurement and small angle light scattering techniques. Rate of crystallization of these blends was found to be slower with increasing amount of PC. The Avrami exponent n for the blends was calculated and related to the shape of superstructures formed. Hv and Vv scattering patterns as seen by small angle light scattering were analyzed to determine the nature, shape, and size of the superstructures. The changes in the superstructure formation with increasing amount of PC in these blends have been analyzed. Copyright © 1990 John Wiley & Sons, Inc.
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页码:1251 / 1264
页数:14
相关论文
共 23 条
[1]   X-RAY STUDIES OF CRYSTAL-STRUCTURE OF POLYBUTYLENETEREPHTHALATE [J].
ALTER, U ;
BONART, R .
COLLOID AND POLYMER SCIENCE, 1976, 254 (03) :348-357
[2]  
AVRAMI M, 1940, J CHEM PHYS, V8, P2123
[3]  
BIRLEY AW, 1984, BR POLYM J, V77, P16
[4]  
BRANDRUP J, 1978, POLYM HDB
[5]   DUCTILE TEARING INSTABILITY IN SOME ENGINEERING THERMOPLASTIC BLENDS [J].
DEKKERS, MEJ ;
HOBBS, SY .
POLYMER ENGINEERING AND SCIENCE, 1987, 27 (15) :1164-1169
[6]  
DELLIMOY D, 1988, POLYM ENG SCI, V28, P104
[7]  
GARG SN, 1981, MAKROMOL CHEM-RAPID, V2, P271
[8]   EFFECT OF CHEMICAL STRUCTURE ON CRYSTALLIZATION RATES AND MELTING OF POLYMERS .1. AROMATIC POLYESTERS [J].
GILBERT, M ;
HYBART, FJ .
POLYMER, 1972, 13 (07) :327-&
[9]  
GILBERT M, 1974, POLYMER, V15, P408
[10]   TOUGHENED BLENDS OF POLY(BUTYLENE TEREPHTHALATE) AND BPA POLYCARBONATE .1. MORPHOLOGY [J].
HOBBS, SY ;
DEKKERS, MEJ ;
WATKINS, VH .
JOURNAL OF MATERIALS SCIENCE, 1988, 23 (04) :1219-1224